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Contract number
075-15-2022-1113
Time span of the project
2022-2024
Invited researcher

As of 01.12.2023

20
Number of staff members
13
scientific publications
4
Objects of intellectual property
General information
Name of the project:

New radiation phenomena in gallium oxide and their application in devices.
Goals and objectives

Goals of project:

Understanding how high concentrations of point defects and associated elastic stresses in Ga2O3-based wide-band semiconductors can overcome the main disadvantages of the Ga2O3 system: low thermal conductivity, absence of impurities or defects that create effective hole conductivity, pronounced polymorphism and the difficulty of combining different polymorphs in one device to maximize the positive effects given by each polymorph, strong metastability of properties.

Project objective:

  1. Active use of radiation defects created by ion implantation.
  2. Control and optimization of this process to obtain the required material properties.
The practical value of the study

Scientific results:

  • Features of the behavior of devices based on ultra-wide bandgap materials have been revealed when the size of the active region is reduced by dry etching (for GaN)
  • for the first time, using the methods of photoelectric spectroscopy of deep levels and positron annihilation, the patterns of radiation defect formation in high-resistivity films of the alpha polymorph Ga2O3 under irradiation with protons and carbon were studied;
  • the formation of a two-dimensional hole gas in heterojunctions of kappa polymorph modification of gallium oxide was demonstrated for the first time;
  • for the first time, the electrical characteristics of layers of gamma-polymorphic modification of gallium oxide formed by implantation of gallium into a beta-polymorph Ga2O3 followed by Si implantation and hydrogen plasma treatment, the nature of important defects formed in beta-Ga2O3 during high-temperature annealing in hydrogen has been studied.
  • For the first time, proton irradiation of Schottky diodes based on the gamma polymorph was carried out, a comparison was made with the beta polymorph, the increased radiation resistance of gamma-Ga2O3 was proven;
  • for the first time, a domestic p-GaN/n-β-GaO3 heterojunction was manufactured, and the potential for using such heterojunctions for power applications, where breakdown voltages reach tens of kV, was assessed.

Organizational and infrastructural changes:

The laboratory of ultra-wide bandgap semiconductors has been opened at NUST MISIS.

Education and personnel occupational retraining:

Kochkova Anastasiia defended her PhD thesis “Investigation of Electric Characteristics and Spectra of Deep Centers in Bulk Crystals and Epitaxial Films of β-Ga2O3

Cooperation:

  1. Institute of Microelectronics Technology and High-Purity Materials Russian Academy of Sciences (IMT RAS), Russia
  2. Ioffe Institute, Russia
  3. Perfect Crystals, Russia
  4. Korea University, Republic of Korea
  5. Hubei University, China 

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A.Y. Polyakov, A. Kuznetsov, A. Azarov, A.V. Miakonkikh, A.V. Chernykh, A.A. Vasilev, I.V. Shchemerov, A.I. Kochkova, N.R. Matros, and S.J. Pearton
The effects of hydrogenation on the properties of heavy ion irradiated b-Ga2O3, J. Mater. Sci: Mater Electron , 2023
E.B. Yakimov, A.Y. Polyakov, V.I. Nikolaev, A.I. Pechnikov, M.P. Scheglov, E.E. Yakimov, S.J. Pearton
Electrical and Recombination Properties of Polar Orthorhombic κ-Ga2O3 Films Prepared by Halide Vapor Phase Epitaxy, Nanomaterials, 2023
A.Y. Polyakov; E.B. Yakimov, D.S. Saranin, A.V. Chernykh, A.A. Vasilev, P. Gostishchev, A.I. Kochkova, L.A. Alexanyan, N.R. Matros, I.V. Shchemerov, S.J. Pearton
Trap states and carrier diffusion lengths in NiO/β-Ga2O3 heterojunctions, Journal of Applied Physics, 2024
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